Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate FeIII complex with a N3O3 coordination sphere
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چکیده
منابع مشابه
The Role of Coulomb Interactions for Spin Crossover Behaviors and Crystal Structural Transformation in Novel Anionic Fe(III) Complexes from a -Extended ONO Ligand
To investigate the π-extension effect on an unusual negative-charged spin crossover (SCO) FeIII complex with a weak N2O4 first coordination sphere, we designed and synthesized a series of anionic FeIII complexes from a π-extended naphthalene derivative ligand. Acetonitrile-solvate tetramethylammonium (TMA) salt 1 exhibited an SCO conversion, while acetone-solvate TMA salt 2 was in a high-spin s...
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Narsimhulu Pittala1, Smail Triki1, Franck Thétiot1, Kamel Boukheddaden2, Guillaume Chastanet3, Mathieu Marchivie3 1Department Of Chemistry, UMR CNRS 6521, Université De Bretagne Occidentale (UBO), Brest, France, 2Groupe d\'étude de la matière condensée (GEMaC), Université de Versailles Saint-Quentin, Versailles, France, 3CNRS, Université Bordeaux, ICMCB, UPR 9048, Bordeaux, France E-mail: narsi...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2017
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c7dt01030c